Dr Benson Kariuki
Teams and roles for Benson Kariuki
Senior Experimental Officer in X-Ray Crystallography.
Overview
- Structure: Polymorphism, supra-molecular assembly and structure-property relationships.
- Solid state processes: crystal growth, phase transformations and solid state reactivity.
- Materials: From organic salts to host-guest complexes.
- Diffraction: Single crystal diffraction, powder diffraction and diffraction physics.
For more information, click on the 'Research' tab above.
Publication
2026
- Abdel-Wahab, B. F. et al., 2026. Impact of substituents on bromination sites of (E)-1-[5-methyl-1-aryl-1H-1,2,3-triazol-4-yl]-3-arylprop-2-en-1-ones using N-bromosuccinimide: Synthesis and crystal structure elucidation. Journal of Molecular Structure 1350 144172. (10.1016/j.molstruc.2025.144172)
- Nchioua, I. et al., 2026. A simple phase‐transfer‐catalyzed mild N1‐methylation of isatin for 1‐methylindoline‐2,3‐dione: X‐ray crystallography, topological analysis, molecular electronic property investigation, and COSMO‐RS modeling. Journal of Molecular Structure 1349 (Part 3) 143848. (10.1016/j.molstruc.2025.143848)
2025
- Abbas, H. F. et al., 2025. Crystal structure of bis ((1-((E)-((4-methoxyphenyl)imino)methyl)naphthalen-2-yl)oxy) copper(II), C36H28CuN2O4. Zeitschrift für Kristallographie - New Crystal Structures 240 (2), pp.247-249. (10.1515/ncrs-2024-0449)
- Abdel-Wahab, B. F. et al., 2025. Synthesis and anticancer evaluation of new 3-allyl-N-(4-fluorophenyl)-4-substituted thiazol-2(3H)-imines on A431 skin cancer cells, revealing cytotoxicity, apoptosis, and cell cycle modulation. Journal of Molecular Structure 1346 143195. (10.1016/j.molstruc.2025.143195)
- Aboshouk, D. R. et al., 2025. Design and synthesis of antiproliferative 2-oxoindolin-3-ylidenes incorporating urea function with potential VEGFR-2 inhibitory properties.. Scientific Reports 15 (1) 618. (10.1038/s41598-024-82005-6)
- Ahmed, D. S. et al., 2025. Evaluation of ultraviolet stability and surface properties of poly(methyl methacrylate) doped with metal oxide nanoparticles. Polymer Korea 49 (2), pp.197-204. (10.7317/pk.2025.49.2.197)
- Ali, B. S. et al., 2025. Further insights into the multitarget anticancer activity of tetrahydrocarbazole-1-amine/5-arylidene-4-thiazolinone based hybrids. Bioorganic Chemistry 164 108853. (10.1016/j.bioorg.2025.108853)
- Allah, A. E. M. A. et al., 2025. Synthesis, X-ray crystallography, COSMO-RS, and molecular electronic property investigation of a novel N-alkyl-substituted 5-chloroisatin derivative. Journal of Molecular Structure 1344 142995. (10.1016/j.molstruc.2025.142995)
- Alsfouk, A. A. et al., 2025. Synthesis, characterization, crystal structure and anti-proliferative properties of curcumin mimic conjugates. Synthetic Communications 55 (13), pp.1029-1043. (10.1080/00397911.2025.2520609)
- Althobaiti, H. A. A. et al., 2025. Stereo-control in Zn(II) and Cd(II) complexes of tetraamines with azacyclic cores. Inorganics 13 (12) 393. (10.3390/inorganics13120393)
- Ati, M. H. et al., 2025. 2-{(E)-[(2-Hydroxy-1-phenylethyl)imino]methyl}-4-[(E)-(4-methylphenyl)diazenyl]phenol. IUCrData 10 (7) x250599. (10.1107/s2414314625005991)
- Baldwin, A. et al. 2025. Tetrahydropyrazolopyridinones as a novel class of potent and highly selective LIMK inhibitors. Journal of Medicinal Chemistry 68 (16), pp.17427-17456. (10.1021/acs.jmedchem.5c00974)
- Bekheit, M. S. et al., 2025. Antineoplastic 4-piperidone-1-phosphonothioates with potential multi-targeted inhibitory properties. Scientific Reports 15 (1) 40363. (10.1038/s41598-025-25796-6)
- Bhattacherjee, D. et al. 2025. Synthesis and reactivity of six‐membered cyclic diaryl λ3‐bromanes and λ3‐chloranes. Angewandte Chemie 64 (14) e202424559. (10.1002/ange.202424559)
- Dhanpat, S. A. et al., 2025. Novel ditopic Schiff base rhenium(I) metallorectangle: synthesis, characterization, and chemical sensing of aromatic hydrocarbons (AHCs). Journal of the Indian Chemical Society 102 (10) 102011. (10.1016/j.jics.2025.102011)
- El Moutaouakil Ala Allah, A. et al., 2025. Synthesis, crystal structure and Hirshfeld surface analysis of 2-azido-N-(2,6-dimethylphenyl)acetamide. Acta Crystallographica Section E: Crystallographic Communications 81 (Pt 7), pp.627-631. (10.1107/s2056989025004530)
- El Moutaouakil Ala Allah, A. et al., 2025. Synthesis, crystal structure and Hirshfeld surface analysis of 5,5-diphenyl-2-[2-(propan-2-ylidene)hydrazin-1-yl]-4,5-dihydro-1H-imidazol-4-one N,N-dimethylformamide hemisolvate. Acta Crystallographica Section E: Crystallographic Communications 81 (Pt 2), pp.109-113. (10.1107/s2056989025000076)
- Erfan, A. et al., 2025. Cytotoxic and apoptotic effects of Tin(IV) complexes containing a Schiff base derived from cephalexin on a breast cancer cell line. Indian Journal of Clinical Biochemistry 40 , pp.434-444. (10.1007/s12291-024-01207-x)
- Gauttier, R. et al., 2025. In-situ solid-state NMR spectroscopy reveals competing crystallization pathways for a system that forms structurally diverse multicomponent crystalline phases. Solid State Nuclear Magnetic Resonance 140 102046. (10.1016/j.ssnmr.2025.102046)
- Hassan, S. M. et al., 2025. Antiproliferation, 3D-multicellular spheroid and VEGFR-2 inhibitory properties of spiroindolin-2-ones with phosphonate function. Scientific Reports 15 (1) 35018. (10.1038/s41598-025-20712-4)
- Hughes, C. E. et al. 2025. Solid-state structure of xanthine determined by a combination of 3D electron diffraction, powder x-ray diffraction, and DFT-D calculations. Crystal Growth and Design 25 (4), pp.895-902. (10.1021/acs.cgd.4c01717)
- Ibraheem, H. et al., 2025. Enhancing photostability of chemically modified poly(vinyl chloride) through the incorporation of organotin moieties on the polymeric chains. Trends in Sciences 22 (4) 9413. (10.48048/tis.2025.9413)
- Maimoune, I. et al., 2025. Crystal structure and Hirshfeld surface analysis of N-(4-nitro-phen-yl)-2-(piperidin-1-yl)acetamide (lidocaine analogue).. Acta Crystallographica Section E: Crystallographic Communications 81 (Pt 1), pp.69-73. (10.1107/s205698902401185x)
- Mohamed-Ezzat, R. A. et al., 2025. Synthesis and crystal structure of piperidinyl propanenitrile towards the preparation of piperidine based bioactive films for drug delivery applications.. Scientific Reports 15 (1) 705. (10.1038/s41598-024-81996-6)
- Mohamed-Ezzat, R. A. et al., 2025. Synthesis and crystal structure of 5-{(E)-[(1H-indol-3-ylformamido)imino]methyl}-2-methoxyphenyl propane-1-sulfonate. Acta Crystallographica Section E: Crystallographic Communications 81 (Pt 4), pp.310-313. (10.1107/s2056989025002087)
- Newman, P. D. et al. 2025. Stereogenic-at-metal Ir(III) complexes as platforms for the construction of asymmetric bimetallic complexes. Inorganic Chemistry (10.1021/acs.inorgchem.5c04469)
- Riseley, R. et al., 2025. Unusual reactivity of 2-amino-1H-indole-3-carboxylate esters. ARKIVOC 2025 (5) 202512417. (10.24820/ark.5550190.p012.417)
2024
- Abdel-Wahab, B. F. , Kariuki, B. M. and El-Hiti, G. A. 2024. Synthesis, isomorphism, and polymorphism of new (2E,4E)-1-(5-methyl-1-aryl-1H-1,2,3-triazol-4-yl)-5-phenylpenta-2,4-dien-1-ones. Journal of Molecular Structure 1304 137748. (10.1016/j.molstruc.2024.137748)
- Abdel-Wahab, B. F. et al., 2024. Synthesis and characterization of new heterocycles containing the 1,2,3-triazole ring system. Journal of Molecular Structure 1311 138404. (10.1016/j.molstruc.2024.138404)
- Abdel-Wahab, B. F. et al., 2024. ( E )-1-(4-Methoxyphenyl)-5-methyl-4-(1-phenyl-4-((2-(2,4,6-trichlorophenyl)hydrazineylidene)methyl)-1 H -pyrazol-3-yl)-1 H -1,2,3-triazole. Molbank 2024 (2) M1798. (10.3390/m1798)
- Abdel-Wahab, B. F. et al., 2024. 1-(2,4-Dinitrophenyl)-2-((Z)-2-((E)-4-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-ylidene)hydrazine. Molbank 2024 (1) M1789. (10.3390/M1789)
- Abdel-Wahab, B. F. et al., 2024. (E)-1-(1-(Benzofuran-2-yl)ethylidene)-2-(2,4,6-trichlorophenyl)hydrazine. Molbank 2024 (1) M1790. (10.3390/M1790)
- Alaboosh, J. M. H. et al. 2024. Crystal structures of sulfonamide protected bicyclic guanidines: (S)-8-{[(tert-butyldimethylsilyl)oxy]methyl}-1-[(2,2,4,6,7-pentamethyl-2,3-dihydrobenzofuran-5-yl)sulfonyl]-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-1-ium trifluoromethanesulfonate and (S)-8-(iodomethyl)-1-tosyl-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-1-ium iodide. Acta Crystallographica Section E: Crystallographic Communications 80 (3), pp.305-309. (10.1107/S2056989024001129)
- Ali, B. S. et al., 2024. Tetrahydrocarbazoles incorporating 5-arylidene-4-thiazolinones as potential antileukemia and antilymphoma targeting tyrosine kinase and tubulin polymerase enzymes: Design, synthesis, structural, biological and molecular docking studies. Bioorganic Chemistry 153 107817. (10.1016/j.bioorg.2024.107817)
- Alotaibi, N. et al. 2024. B(C6F5)3-catalysed alkylation of imidazo[1,2-a]pyridines using α,β-unsaturated ketones. European Journal of Organic Chemistry 27 (12) e202400022. (10.1002/ejoc.202400022)
- Bekheit, M. S. et al., 2024. Novel sulfonamide-phosphonate conjugates as carbonic anhydrase isozymes inhibitors. Drug Development Research 85 (1) e22135. (10.1002/ddr.22135)
- Cubitt, J. et al. 2024. Beware of N-Benzoyloxybenzamides. Molecules 29 (21) 5143. (10.3390/molecules29215143)
- Edwards, L. et al. 2024. Deville rebooted – practical N 2 O 5 synthesis †. Chemical Communications 60 (46), pp.5920-5923. (10.1039/d4cc01403k)
- El Moutaouakil Ala Allah, A. et al., 2024. Synthesis, crystal structure and Hirshfeld surface of ethyl 2-[2-(methylsulfanyl)-5-oxo-4,4-diphenyl-4,5-dihydro-1H-imidazol-1-yl]acetate (thiophenytoin derivative). Acta Crystallographica Section E: Crystallographic Communications 80 (9), pp.926-930. (10.1107/S2056989024007345)
- El Moutaouakil Ala Allah, A. et al., 2024. 2-Chloro-N-(4-hydroxyphenyl)acetamide. IUCrData 9 (10) x241015. (10.1107/S2414314624010150)
- Ibraheem, H. A. et al., 2024. Investigation of the impact of chemical modifications on the photostability of polymethyl methacrylate. International Journal of Polymer Science 2024 3354280. (10.1155/2024/3354280)
- Ibraheem, H. A. et al., 2024. Modified polymethyl methacrylate as a sustainable medium for capturing carbon dioxide. Materials Letters 372 137031. (10.1016/j.matlet.2024.137031)
- Jima'a, R. et al., 2024. Synthesis and properties of new metal complexes containing heterocyclic moieties and investigation of the role of the metal in carbon dioxide gas capture. Journal of Materials Protection 65 (4), pp.734-747. (10.62638/ZasMat1045)
- Koutentis, P. A. et al., 2024. Variation of the bromination site on the reaction of (E)-1-[5-methyl-1-(aryl)-1H-1,2,3-triazol-4-yl]-3-arylprop-2-en-1-ones with N-bromosuccinimide. ARKIVOC 2024 (1) 12214. (10.24820/ark.5550190.p012.214)
- Mohamed-Ezzat, R. A. , Kariuki, B. M. and Elgemeie, G. H. 2024. Synthesis and crystal structure of N-phenyl-2-(phenylsulfanyl)acetamide. Acta Crystallographica Section E: Crystallographic Communications 80 (4), pp.392-395. (10.1107/S2056989024002573)
- Mohamed‐Ezzat, R. , Kariuki, B. and Azzam, R. 2024. Discovery of promising sulfadiazine derivatives with anti‐proliferative activity against tumor cell lines. Journal of Heterocyclic Chemistry 61 (12), pp.1980-1998. (10.1002/jhet.4893)
- Newman, P. D. et al. 2024. A noble nexus: a phosphino-phen ligand for tethering precious metals †. Dalton Transactions 53 (37)(10.1039/d4dt02130d)
- Pahar, S. et al. 2024. Diverse reactivity of amidinate-supported boron centers with the hypersilyl anion and access to a monomeric secondary boron hydride. Inorganic Chemistry 63 (18), pp.8302–8311. (10.1021/acs.inorgchem.4c00612)
- Platts, J. A. , Kariuki, B. M. and Newman, P. D. 2024. Welcoming neighbour or inhospitable host? Selective second metal binding in 5- and 6-phospha-substituted Bpy ligands. Molecules 29 (5) 1150. (10.3390/molecules29051150)
- Rahim, S. et al., 2024. In vitro anticancer, antioxidant, antimicrobial, antileishmanial, enzymes inhibition and in vivo anti-inflammatory activities of organotin(IV) derivatives of 4-bromophenoxyacetic acid. Journal of Molecular Structure 1313 (5) 138703. (10.1016/j.molstruc.2024.138703)
- Sama, F. J. et al. 2024. Backbone-functionalised ruthenium diphosphine complexes for catalytic upgrading of ethanol and methanol to iso-butanol †. Dalton Transactions 53 (18), pp.8005-8010. (10.1039/d4dt00561a)
- Vladimirov, V. Y. et al. 2024. Ringing the changes: Effects of heterocyclic ring size on stereoselectivity in [(η5-C5Me5)RhCl], [(η5-C5Me5)IrCl] and [Ru(η6-cymene)Cl] complexes of chiral 3-Amino-1-Azacycles. Molecules 29 (19) 4659. (10.3390/molecules29194659)
- Wagner, A. et al., 2024. Rationalizing the influence of small-molecule dopants on guanine crystal morphology. Chemistry of Materials 36 (18), pp.8910–8919. (10.1021/acs.chemmater.4c01771)
- Wagner, A. et al., 2024. Structure determination of biogenic crystals directly from 3D electron diffraction data. Crystal Growth and Design 24 (3), pp.899-905. (10.1021/acs.cgd.3c01290)
2023
- Abdel-Wahab, B. F. et al., 2023. Crystal structure of (Z)-3-(3-(4-hydroxyphenyl)-2-(phenylimino)-2,3-dihydrothiazol-4-yl)-2H-chromen-2-one, C24H16N2O3S. Zeitschrift für Kristallographie - New Crystal Structures 239 (1), pp.151-153. (10.1515/ncrs-2023-0504)
- Abdel-Wahab, B. F. et al., 2023. Crystal structure of (Z)-3-(4-methoxyphenyl)-4-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-N-phenylthiazol-2(3H)-imine, C25H21N5OS. Zeitschrift für Kristallographie - New Crystal Structures 239 (1), pp.147-149. (10.1515/ncrs-2023-0503)
- Abdel-Wahab, B. F. et al., 2023. ( E )- N’ -(1-(Benzofuran-2-yl)ethylidene)-1-(4-Methoxyphenyl)-5-Methyl-1 H -1,2,3-Triazole-4-Carbohydrazide. Molbank 2023 (2) M1657. (10.3390/m1657)
- Abdel-Wahab, B. F. et al., 2023. (E)-5-(4-Methoxyphenyl)-N?-(2-oxoindolin-3-ylidene)-1-phenyl-1H-pyrazole-3-carbohydrazide. IUCrData 8 (5) x230455. (10.1107/S2414314623004558)
- Abdel-Wahab, B. F. et al., 2023. ( E )-1-(5-methyl-1-(4-nitrophenyl)-1 H -1,2,3-triazol-4-yl)ethan-1-one oxime. Molbank 2023 M1593. (10.3390/m1593)
- Abdel-Wahab, B. F. et al., 2023. Catalyst-free synthesis of Novel 4-(Benzofuran-2-yl)- N -phenylthiazol-2(3 H )-imines, crystal structure elucidation, and the effect of phenyl substitution on crystal packing. Crystals 13 (8) 1239. (10.3390/cryst13081239)
- Abdel-Wahab, B. F. et al., 2023. Synthesis and anticancer activity of 3-(1-aryl-5-methyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazole-4-carbaldehydes. Journal of Molecular Structure 1294 136528. (10.1016/j.molstruc.2023.136528)
- Abdel-Wahab, B. F. et al., 2023. Synthesis of new derivatives of the 1H-1,2,3-triazole ring using 1-aryl-5-phenyl-1H-1,2,3-triazole-4-carbohydrazides as precursors. ARKIVOC (7)(10.24820/ark.5550190.p012.020)
- Abdel-Wahab, B. F. et al., 2023. (2 Z,5 Z )-5-((3-(Benzofuran-2-yl)-1-phenyl-1 H -pyrazol-4-yl)methylene)-2-((4-methoxyphenyl)imino)-3-phenylthiazolidin-4-one. Molbank 2023 (2) M1665. (10.3390/m1665)
- Al Rahal, O. et al. 2023. Unraveling the Complex Solid-State Phase Transition Behavior of 1-Iodoadamantane, a Material for Which Ostensibly Identical Crystals Undergo Different Transformation Pathways. Crystal Growth and Design 23 (5), pp.3820-3833. (10.1021/acs.cgd.3c00223)
- Arraq, R. R. et al., 2023. Enhancement of photostabilization of poly(vinyl chloride) in the presence of tin–cephalexin complexes. Polymers 15 (3) 550. (10.3390/polym15030550)
- Bekheit, M. S. et al., 2023. Spiroindole-containing compounds bearing phosphonate group of potential Mpro-SARS-CoV-2 inhibitory properties. European Journal of Medicinal Chemistry 258 115563. (10.1016/j.ejmech.2023.115563)
- Emad, N. et al., 2023. Metal oxide nanoparticles containing clotrimazole to suppress photodegradation of poly(vinyl chloride) thin films. Polymers 15 (7) 1632. (10.3390/polym15071632)
- Emad, N. et al., 2023. New metal complexes containing a methyldopa Schiff base for carbon dioxide storage. Results in Chemistry 6 101099. (10.1016/j.rechem.2023.101099)
- Emad, N. et al., 2023. Synthesis, physical properties, and carbon dioxide uptake of new metal-sulfamethoxazole complexes. Results in Chemistry 6 101137. (10.1016/j.rechem.2023.101137)
- Girgis, A. S. et al., 2023. Indole-based compounds as potential drug candidates for SARS-CoV-2. Molecules 28 (18) 6603. (10.3390/molecules28186603)
- Hashem, H. E. et al., 2023. Nanoparticles of a pyrazolo-pyridazine derivative as potential EGFR and CDK-2 inhibitors: design, structure determination, anticancer evaluation and in silico studies. Molecules 28 (21) 7252. (10.3390/molecules28217252)
- Kariuki, B. M. et al. 2023. 4-((5-(1-(4-Fluorophenyl)-5-methyl-1H-1,2,3-triazol-4-yl)-1,3,4-thiadiazol-2-yl)amino)benzenesulfonic acid: unexpected synthesis, structure elucidation and antimicrobial activity. Phosphorus, Sulfur, and Silicon and the Related Elements 198 (1), pp.10-14. (10.1080/10426507.2022.2099858)
- Mohamed-Ezzat, R. A. , Kariuki, B. M. and Azzam, R. A. 2023. Synthesis and crystal structure of N-(5-acetyl-4-methylpyrimidin-2-yl)benzenesulfonamide. Acta Crystallographica Section E: Crystallographic Communications 79 (4), pp.331-334. (10.1107/S2056989023001871)
- Mohamed-Ezzat, R. A. , Kariuki, B. M. and Elgemeie, G. H. 2023. Unexpected products of the reaction of cyanoacetylhydrazones of aryl/heteryl ketones with hydrazine: a new route to aryl/heteryl hydrazones, x-ray structure, and in vitro anti-proliferative activity against nci 60-cell line panel. Egyptian Journal of Chemistry 66 (13), pp.225-239. (10.21608/ejchem.2023.197330.7682)
- Mohamed-Ezzat, R. A. , Kariuki, B. M. and Srour, A. M. 2023. Synthesis, crystal structure and in vitro anti-proliferative activity of 2-[(4-acetylphenyl)carbamoyl]phenyl acetate. Acta Crystallographica Section E: Crystallographic Communications 79 (11), pp.999-1002. (10.1107/S2056989023008526)
- Nasr, T. et al., 2023. Synthesis and crystal structures of (E)-N′-(4-chloro-3-nitrobenzylidene)acetohydrazide and (E)-2-(4-chlorobenzylidene)-1-(quinolin-8-yl)hydrazine. Acta Crystallographica Section E: Crystallographic Communications 79 (8), pp.762-766. (10.1107/S2056989023006412)
- Sansul, S. et al., 2023. Pendant modification of poly(methyl methacrylate) to enhance its stability against photoirradiation. Polymers 15 (14) 2989. (10.3390/polym15142989)
- Wright, A. I. , Kariuki, B. M. and Wu, Y. 2023. Synthesis, solid-state structure, and electrochemical properties of thienodipyrimidine-2,4,5,7-tetra(thi)ones. ARKIVOC 2023 (2) 202311998. (10.24820/ark.5550190.p011.998)
- Young, T. B. et al. 2023. Chemically recyclable fluorescent polyesters via the ring-opening copolymerization of epoxides and anhydrides. Polymer Chemistry (10.1039/D3PY00209H)
2022
- Ahmed, D. S. et al., 2022. Fabrication of highly photostable polystyrene films embedded with organometallic complexes. Polymers 14 (5) 1024. (10.3390/polym14051024)
- Fadhil, M. et al., 2022. Synthesis and application of levofloxacin–tin complexes as new photostabilizers for polyvinyl chloride. Polymers 14 (18) 3720. (10.3390/polym14183720)
- Fadhil, M. et al., 2022. Synthesis of new Norfloxacin-Tin complexes to mitigate the effect of ultraviolet-visible irradiation in polyvinyl chloride films. Polymers 14 (14) 2812. (10.3390/polym14142812)
- Fawazy, N. G. et al., 2022. Development of spiro-3-indolin-2-one containing compounds of antiproliferative and anti-SARS-CoV-2 properties. Scientific Reports 12 (1) 13880. (10.1038/s41598-022-17883-9)
- Fayek, M. et al., 2022. Anti-prostate cancer metabolites from the soil-derived Aspergillus neoniveus. Frontiers in Pharmacology 13 1006062. (10.3389/fphar.2022.1006062)
- Ghanim, A. M. et al., 2022. Design and synthesis of ibuprofen-quinoline conjugates as potential anti-inflammatory and analgesic drug candidates. Bioorganic Chemistry 119 105557. (10.1016/j.bioorg.2021.105557)
- Gökce, H. et al., 2022. Quantum Computational Investigation of (E)-1-(4-methoxyphenyl)-5-methyl-N?-(3-phenoxybenzylidene)-1H-1,2,3-triazole-4-carbohydrazide. Molecules 27 (7) 2193. (10.3390/molecules27072193)
- Kariuki, B. M. et al. 2022. Intermolecular interactions of 3,5-bis(4-Methoxyphenyl)-4,5-dihydro-1H-pyrazole-1-carbothioamide in a cocrystal with 1,3-bis(4-Methoxyphenyl)prop-2-en-1-one and dimethylformamide solvate. Crystals 12 (5) 663. (10.3390/cryst12050663)
- Kariuki, B. M. et al. 2022. (Z)-2-(1-(5-Methyl-1-(4-nitrophenyl)-1H-1,2,3-triazol-4-yl)ethylidene)-N-phenylhydrazine-1-carbothioamide. Molbank 2022 (4) M1462. (10.3390/m1462)
- Kariuki, B. M. et al. 2022. ( E )-1-(5-methyl-1-(4-nitrophenyl)-1 H -1,2,3-triazol-4-yl)-3-(naphthalen-2-yl)prop-2-en-1-one. Molbank 2022 (4) M1464. (10.3390/m1464)
- Kariuki, B. M. et al. 2022. Synthesis and characterization of novel 2-(1,2,3-triazol-4-yl)-4,5-dihydro-1 h -pyrazol-1-yl)thiazoles and 2-(4,5-dihydro-1 h -pyrazol-1-yl)-4-(1 h -1,2,3-triazol-4-yl)thiazoles. Molecules 27 (24) 8904. (10.3390/molecules27248904)
- Kariuki, B. M. et al. 2022. Synthesis and structure determination of 2-cyano-3-(1-phenyl-3-(thiophen-2-yl)-1 H -pyrazol-4-yl)acrylamide. Molbank 2022 (2) eM1372. (10.3390/m1372)
- Mohamed, H. A. et al., 2022. Synthesis and antimicrobial activity of 2,5-bis(Pyrazol-3-yl or Triazol-4-yl)-1,3,4-oxadiazoles. Heterocycles 104 (7), pp.1293-1302. (10.3987/COM-22-14676)
- Mohamed-Ezzat, R. A. , Kariuki, B. M. and Azzam, R. A. 2022. Morpholin-4-ium [5-cyano-6-(4-methylphenyl)-4-(morpholin-4-yl)pyrimidin-2-yl](phenylsulfonyl)amide. IUCrData 7 (11) x221033. (10.1107/S2414314622010331)
- Naoom, N. et al., 2022. Synthesis of methyldopa–tin complexes and their applicability as photostabilizers for the protection of polyvinyl chloride against photolysis. Polymers 14 (21) 4590. (10.3390/polym14214590)
- Sabry, E. et al., 2022. Microwave-assisted synthesis of novel sulfonamide-based compounds bearing α-aminophosphonate and their antimicrobial properties. Journal of Molecular Structure 1266 133553. (10.1016/j.molstruc.2022.133553)
- Saleh, T. A. et al., 2022. Monitoring physicochemical properties of transparent PVC films containing captopril and metal oxide nanoparticles to assess UV blocking. Journal of Polymer Research 29 (6) 249. (10.1007/s10965-022-03097-0)
- Smith, K. et al. 2022. Polybromination of naphthalene using bromine over a montmorillonite clay and regioselective synthesis of 2,6-dibromonaphthalene. ARKIVOC 2022 (5), pp.46-59. (10.24820/ark.5550190.p011.717)
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2018
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2017
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2011
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2010
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2009
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2008
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2007
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2006
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2005
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2004
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Conferences
- Arora, M. et al. 2017. Polymorphic adaptation. Presented at: 17th International Conference, CAAD Futures 2017 Istanbul 12-14 July 2017. Published in: Çağdaş, G. et al., Future Trajectories of Computation in Design. Istanbul: Istanbul Technical University. , pp.474-491.
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Research
Polymorphs are fascinating because they represent special cases where the delicate balance between intra-crystal interactions gives rise to alternative results. Investigation of polymorphism provides some insight into the subtle interplay between the forces involved. An understanding of such interactions and the resulting structural patterns is clearly a prerequisite to materials design.
Of particular interest is reactivity in the solid state, with the ideal process occurring in crystalline materials. The results can be starkly different in comparison to reactions in the fluid state; for example, unique products may be obtained in pure form, i.e. uncontaminated by impurities or solvents. A distinct product may also be obtained for each form in polymorphic systems. An aim of the research in this area is to understand and subsequently control the crystallisation process in order to influence the reaction products.
Teaching
CH0004 Inorganic and Redox Chemistry
CH3104 Introduction to the Solid State and Applications of Spectroscopy
CH2112 Forensic Chemistry
CH3407 Advanced Materials
Biography
PhD, University of Cambridge (1990, W. Jones, Organic Solid State Chemistry). Postdoctoral Research Fellow, University of Liverpool (1990-94), University College London (1994-95), University of Birmingham (1995-99). Research Fellow in X-ray Diffraction, University of Birmingham (1999-2008). Appointed Senior Lecturer in X-ray Crystallography, Cardiff, 2008.