Professor Simon Pope
- Available for postgraduate supervision
Teams and roles for Simon Pope
Professor of Inorganic Chemistry and Director of PGR
Overview
- luminescent complexes for targeted biological imaging
- photoactive materials for lighting harvesting and energy applications
- earth abundant metal complexes for energy applications
- development of carbon nanomaterials
For more information, click on the 'Research' tab above.
Publication
2025
- Alkhaibari, I. et al. 2025. DNA‐binding properties of non‐intercalating water‐soluble organometallic Ir(III) luminophores. Chemistry - A European Journal 31 (30) e202500290. (10.1002/chem.202500290)
- Ibbott, A. R. et al. 2025. Combined colourimetric and turn-on luminescence from a redox-switchable 2-aza-anthraquinone bridged dimetallic assembly. Dalton Transactions 54 , pp.15986-15990. (10.1039/D5DT02287H)
- Ibbott, A. R. et al. 2025. Luminescent Ru(II) complexes based on functionalised 1,10-phenanthroline derivatised ligands towards bioconjugated probes. Inorganica Chimica Acta 579 122561. (10.1016/j.ica.2025.122561)
- Newman, P. D. et al. 2025. Stereogenic-at-metal Ir(III) complexes as platforms for the construction of asymmetric bimetallic complexes. Inorganic Chemistry (10.1021/acs.inorgchem.5c04469)
- Payce, E. N. et al. 2025. Energy upconversion using platinum(II)-BPI photosensitizers. Inorganic Chemistry (10.1021/acs.inorgchem.5c04677)
- Rainbow, J. et al., 2025. Electrochemical signal amplification for pathogen nucleic acid detection utilizing a cobalt-based DNA-binding metallo-intercalator. Sensors & Diagnostics 4 (6), pp.519-528. (10.1039/D4SD00322E)
2024
- Alkhaibari, I. S. et al. 2024. Tuning excited state character in iridium(III) photosensitizers and its influence on TTA-UC. Inorganic Chemistry 63 (21), pp.9931-9940. (10.1021/acs.inorgchem.4c01003)
- Amoroso, A. J. and Pope, S. J. 2024. Lanthanides for luminescent and magnetic resonance imaging. In: Feng, L. and James, T. D. eds. Imaging Tools for Chemical Biology. Chemical Biology Royal Society of Chemistry. , pp.48-70. (10.1039/9781837673117-00048)
- Knighton, R. C. and Pope, S. J. A. 2024. Synthesis and luminescent properties of hetero-bimetallic and hetero-trimetallic Ru( ii )/Au( i ) or Ir( iii )/Au( i ) complexes. Dalton Transactions 53 , pp.4165-4174. (10.1039/d3dt03690a)
- Newman, P. D. et al. 2024. A noble nexus: a phosphino-phen ligand for tethering precious metals †. Dalton Transactions 53 (37)(10.1039/d4dt02130d)
- Payce, E. N. et al. 2024. Luminescent Pt(II) complexes using unsymmetrical Bis(2-pyridylimino)isoindolate analogues. Inorganic Chemistry 63 (18), pp.8273–8285. (10.1021/acs.inorgchem.4c00558)
- Stokes, E. C. et al. 2024. Alkyl chain functionalised Ir(iii) complexes: synthesis, properties and behaviour as emissive dopants in microemulsions. RSC Advances 14 (10), pp.6987-6997. (10.1039/D3RA06764E)
2023
- Elgar, C. et al. 2023. Deep red emitting heteroleptic Ir(III) complexes that incorporate unsymmetrical 4-quinoline carboxylic acid derived ligands. European Journal of Inorganic Chemistry 26 (18) e202300102. (10.1002/ejic.202300102)
- Fenn, G. D. et al. 2023. Development of a novel anthraquinone-derived fluorescent lysosomal probe. Molecular Genetics and Metabolism 138 (2) 107097. (10.1016/j.ymgme.2022.107097)
- Fitzgerald, S. A. et al. 2023. 2-(Thienyl)quinoxaline derivatives and their application in Ir( iii ) complexes yielding tuneable deep red emitters †. Dalton Transactions 52 (44), pp.16480-16480. (10.1039/d3dt02193a)
- Knighton, R. C. , Beames, J. M. and Pope, S. J. A. 2023. Polycationic Ru(II) luminophores: syntheses, photophysics, and application in electrostatically driven sensitization of lanthanide luminescence. Inorganic Chemistry 62 (48), pp.19446-19456. (10.1021/acs.inorgchem.3c02352)
- Young, T. B. et al. 2023. Chemically recyclable fluorescent polyesters via the ring-opening copolymerization of epoxides and anhydrides. Polymer Chemistry (10.1039/D3PY00209H)
2022
- Al-Riyahee, A. A. A. et al. 2022. N,N′-Substituted thioureas and their metal complexes: syntheses, structures and electronic properties. Dalton Transactions 51 (9), pp.3531-3545. (10.1039/D1DT04091J)
- Al-Riyahee, A. A. et al., 2022. Ni(II), Cu(II) and Zn(II) complexes of functionalised thiosemicarbazone ligands: Syntheses and reactivity, characterization and structural studies. Polyhedron 225 116079. (10.1016/j.poly.2022.116079)
- Bonello, R. O. et al. 2022. Aryl, bi-functionalised imidazo[4,5-f]-1,10-phenanthroline ligands and their luminescent rhenium(I) complexes. Polyhedron 228 116179. (10.1016/j.poly.2022.116179)
- Fitzgerald, S. A. et al. 2022. Organometallic platinum(ii) photosensitisers that demonstrate ligand‐modulated triplet‐triplet annihilation energy upconversion efficiencies. Chemistry - A European Journal e202203241. (10.1002/chem.202203241)
- Sawicka, N. et al. 2022. Long-lived, near-IR emission from Cr(iii) under ambient conditions. Chemical Communications 58 (38), pp.5733-5736. (10.1039/D2CC01434C)
2021
- Díaz-Ortega, I. F. et al., 2021. Monitoring spin-crossover phenomena via Re(i) luminescence in hybrid Fe(ii) silica coated nanoparticles. Dalton Transactions 50 , pp.16176-16184. (10.1039/D1DT03334D)
- Fitzgerald, S. A. et al. 2021. Polysubstituted ligand framework for color tuning phosphorescent iridium(III) complexes. Inorganic Chemistry 60 (20), pp.15467-15484. (10.1021/acs.inorgchem.1c02121)
- Otaif, H. Y. et al. 2021. Bis-cyclometalated iridium(iii) complexes with terpyridine analogues: syntheses, structures, spectroscopy and computational studies. RSC Advances 11 (63), pp.39718–39727. (10.1039/D1RA07213G)
- Pope, S. J. et al. 2021. Iridium(III) sensitizers and energy upconversion: the influence of ligand structure upon TTA-UC performance. Chemistry - A European Journal 27 (10), pp.3427-3439. (10.1002/chem.202004146)
2020
- Cantos, P. M. , Pope, S. J. A. and Cahill, C. L. 2020. Correction: An exploration of homo- and heterometallic UO22+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies. CrystEngComm 22 (29) 4952. (10.1039/D0CE90092C)
- Day, A. H. et al. 2020. Towards dual SPECT/optical bioimaging with a mitochondrial targeting, 99mTc(i) radiolabelled 1,8-naphthalimide conjugate. Dalton Transactions 49 (2), pp.511-523. (10.1039/C9DT04024B)
- Day, A. H. et al. 2020. Targeted cell imaging properties of a deep red luminescent iridium(III) complex conjugated with a c-Myc signal peptide. Chemical Science 11 (6), pp.1599-1606. (10.1039/C9SC05568A)
- Edgar, R. J. et al., 2020. Inhibition of the photochromic behaviour of a 3,3-diphenyl-3H-pyrano[3,2-f]quinoline ligand by coordination to Ag(I) ions. Dyes and Pigments 175 108167. (10.1016/j.dyepig.2019.108167)
- Harding, L. P. et al., 2020. A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis. Journal of Chemical Research 44 (11-12), pp.733-737. (10.1177/1747519820917888)
- Lloyd, D. et al. 2020. Functional imaging of a model unicell: Spironucleus vortens as an anaerobic but aerotolerant flagellated protist. Advances in Microbial Physiology 76 , pp.41-79. (10.1016/bs.ampbs.2020.01.002)
- Spencer, J. et al. 2020. CW EPR investigation of red-emitting CaS:Eu phosphors: rationalization of local electronic structure. Advanced Optical Materials 8 (22) 2001241. (10.1002/adom.202001241)
- Stonelake, T. M. et al. 2020. Spectroscopic and theoretical investigation of color tuning in deep-red luminescent iridium(III) complexes. Inorganic Chemistry 59 (4)(10.1021/acs.inorgchem.9b02991)
2019
- Al-Riyahee, A. A. et al. 2019. Syntheses, X-ray structures and characterisation of luminescent chromium(III) complexes incorporating 8-quinolinato ligands. Polyhedron 157 , pp.396. (10.1016/j.poly.2018.10.019)
- Day, A. H. et al. 2019. Synthetic routes, characterization and photophysical properties of luminescent, surface functionalized nanodiamonds. Carbon 152 , pp.335-343. (10.1016/j.carbon.2019.05.081)
- Groves, L. M. et al. 2019. Fluorescent functionalised naphthalimides and their Au(i)–NHC complexes for potential use in cellular bioimaging. Dalton Transactions 48 (5), pp.1599-1612. (10.1039/C8DT04069A)
- Phillips, K. A. et al. 2019. Dual visible/NIR emission from organometallic iridium(III) complexes. Journal of Organometallic Chemistry 893 , pp.11-20. (10.1016/j.jorganchem.2019.04.019)
2018
- Groves, L. M. et al. 2018. Synthesis and characterisation of fluorescent aminophosphines and their coordination to gold(i). Dalton Transactions 47 (28), pp.9324-9333. (10.1039/C8DT02256A)
- Langdon-Jones, E. E. , Ward, B. and Pope, S. 2018. Synthesis and luminescence properties of cyclometalated iridium(III) complexes incorporating conjugated benzotriazole units. Journal of Organometallic Chemistry 861 , pp.234-243. (10.1016/j.jorganchem.2018.02.019)
- Phillips, K. A. et al. 2018. Ligand tuneable, red-emitting iridium(III) complexes for efficient triplet-triplet annihilation upconversion performance. Chemistry - A European Journal 24 (34), pp.8577-8588. (10.1002/chem.201801007)
- Soltani, Y. et al. 2018. Synthesis and photophysical properties of imine borane adducts towards vapochromic materials. Dalton Transactions 47 (36), pp.12656-12660. (10.1039/C8DT03019G)
2017
- Amoroso, A. J. , Fallis, I. A. and Pope, S. J. A. 2017. Chelating agents for radiolanthanides: applications to imaging and therapy. Coordination Chemistry Reviews 340 , pp.198-219. (10.1016/j.ccr.2017.01.010)
- Bonello, R. O. et al., 2017. Synthesis and characterisation of phosphorescent rhenium(I) complexes of hydroxy- and methoxy-substituted imidazo[4,5- f ]-1,10-phenanthroline ligands. Journal of Organometallic Chemistry 841 , pp.39-47. (10.1016/j.jorganchem.2017.04.021)
- Carter, K. P. et al., 2017. Exploring the promotion of synthons of choice: halogen bonding in molecular lanthanide complexes characterized via X-ray diffraction, luminescence spectroscopy, and magnetic measurements. Zeitschrift für ganische und allgemeine Chemie 643 (23), pp.1948-1955. (10.1002/zaac.201700341)
- Cudré, Y. et al., 2017. Tris-heteroleptic iridium complexes based on cyclometalated ligands with different cores. Inorganic Chemistry -American Chemical Society- 56 (19), pp.11565-11576. (10.1021/acs.inorgchem.7b01307)
- Groves, L. M. et al. 2017. From ligand to phosphor: rapid, machine-assisted synthesis of substituted iridium(III) pyrazolate complexes with tuneable luminescence. Chemistry - A European Journal 23 (39), pp.9407-9418. (10.1002/chem.201701551)
- Jana, A. , Pope, S. and Ward, M. D. 2017. D → f energy transfer in heteronuclear Ir(III)/Ln(III) near-infrared luminescent complexes. Polyhedron 127 , pp.390-395. (10.1016/j.poly.2017.02.016)
- Langdon-Jones, E. E. et al., 2017. Luminescent 1,8-Naphthalimide-Derived ReI Complexes: syntheses, spectroscopy, X-ray structure and preliminary bioimaging in fission yeast cells. European Journal of Inorganic Chemistry 2017 (44), pp.5279-5287. (10.1002/ejic.201700549)
- Miletiić, T. et al. 2017. A twisted bay-substituted quaterrylene phosphorescing in the NIR spectral region. Helvetica Chimica Acta 100 (11) e1700192. (10.1002/hlca.201700192)
- Ould, D. M. C. et al. 2017. Investigations into the photophysical and electronic properties of pnictoles and Their pnictenium counterparts. Organometallics 37 (5), pp.712-719. (10.1021/acs.organomet.7b00564)
- Pope, S. J. A. et al. 2017. Anticancer, azonafide-inspired fluorescent ligands and their rhenium(I) complexes for cellular imaging. European Journal of Inorganic Chemistry 2017 (3), pp.759-766. (10.1002/ejic.201601271)
2016
- Bennett, S. D. et al., 2016. Scandium complexes bearing bis(oxazolinylphenyl)amide ligands: an analysis of their reactivity, solution-state structures and photophysical properties. European Journal of Inorganic Chemistry 2016 (18), pp.2932-2941. (10.1002/ejic.201600223)
- Carter, K. P. et al., 2016. Supramolecular assembly of molecular rare-earth–3,5-dichlorobenzoic acid–2,2′:6′,2″-terpyridine materials: structural systematics, luminescence properties, and magnetic behavior. Inorganic Chemistry 55 (14), pp.6902-6915. (10.1021/acs.inorgchem.6b00408)
- Jiménez, J. et al., 2016. Frontispiece: Lanthanide tetrazolate complexes combining single-molecule magnet and luminescence properties: The effect of the replacement of tetrazolate N3 by β-Diketonate Ligands on the anisotropy energy barrier. Chemistry - a European Journal 22 (41)(10.1002/chem.201684162)
- Jiménez, J. et al., 2016. Lanthanide tetrazolate complexes combining single-molecule magnet and luminescence properties: the effect of the replacement of tetrazolate n3 by β-diketonate ligands on the anisotropy energy barrier. Chemistry - A European Journal 22 (41), pp.14548-14559. (10.1002/chem.201601457)
- Lowe, J. A. et al., 2016. Alkyl chain functionalised, cyclometalated platinum(II) complexes: syntheses, luminescence properties and X-ray crystal structure. Journal of Organometallic Chemistry 805 , pp.87-93. (10.1016/j.jorganchem.2016.01.015)
- Stacey, O. J. et al., 2016. Chromophore-labelled, luminescent platinum complexes: syntheses, structures, and spectroscopic properties. Dalton Transactions 45 , pp.10297-10307. (10.1039/C6DT01335J)
- Stacey, O. J. et al., 2016. Near-IR luminescent lanthanide complexes with 1,8-diaminoanthraquinone-based chromophoric ligands. Dalton Transactions 45 (15), pp.6674-6681. (10.1039/C5DT04351D)
2015
- Amoroso, A. J. and Pope, S. J. A. 2015. Using lanthanide ions in molecular bioimaging. Chemical Society Reviews 44 (14), pp.4723-4742. (10.1039/C4CS00293H)
- Carter, K. P. et al., 2015. Controlling dimensionality via a dual ligand strategy in Ln-thiophene-2,5-dicarboxylic acid-terpyridine coordination polymers. Dalton Transactions 44 (36), pp.15843-15854. (10.1039/C5DT02596F)
- Coogan, M. P. and Pope, S. J. A. 2015. Application of d- and f-block fluorescent cell imaging agents. In: Long, N. and Wong, W. eds. The Chemistry of Molecular Imaging. USA: Wiley-Blackwell. , pp.275-298. (10.1002/9781118854754.ch12)
- Herrera, J. M. et al., 2015. Studies on bifunctional Fe(ii)-triazole spin crossover nanoparticles: time-dependent luminescence, surface grafting and the effect of a silica shell and hydrostatic pressure on the magnetic properties. Journal of Materials Chemistry C 3 (30), pp.7819-7829. (10.1039/C5TC00685F)
- Langdon-Jones, E. E. et al. 2015. Alkynyl-naphthalimide fluorophores: gold coordination chemistry and cellular imaging applications. Inorganic Chemistry 54 (13), pp.6606-6615. 150618152106000. (10.1021/acs.inorgchem.5b00954)
- Stacey, O. J. et al. 2015. Water soluble, cyclometalated Pt(II)–Ln(III) conjugates towards novel bimodal imaging agents. Chemical Communications 51 (61), pp.12305-12308. (10.1039/C5CC02623G)
- Stacey, O. J. et al. 2015. Phosphorescent, cyclometalated cinchophen-derived platinum complexes: syntheses, structures, and electronic properties. Inorganic Chemistry 150619121705005. (10.1021/acs.inorgchem.5b00817)
- Stokes, E. C. et al. 2015. Cationic, luminescent cyclometalated iridium(iii) complexes based on substituted 2-phenylthiazole ligands. Dalton Transactions 44 (18), pp.8488-8496. (10.1039/C4DT03054K)
- Thangavelu, S. G. , Pope, S. J. A. and Cahill, C. L. 2015. Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands. Crystengcomm 17 (32), pp.6236-6247. (10.1039/C5CE00984G)
2014
- Bennett, S. D. et al. 2014. Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. Dalton Transactions 43 (15), pp.5871-5885. (10.1039/c4dt00114a)
- Bonello, R. O. et al. 2014. Luminescent rhenium(I) complexes of substituted imidazole[4,5-f]-1,10-phenanthroline derivatives. Journal of Organometallic Chemistry 749 , pp.150-156. (10.1016/j.jorganchem.2013.08.031)
- Carter, K. P. , Pope, S. J. A. and Cahill, C. L. 2014. A series of Ln-p-chlorobenzoic acid-terpyridine complexes: lanthanide contraction effects, supramolecular interactions and luminescent behavior. CrystEngComm 16 (10), pp.1873-1884. (10.1039/c3ce42267d)
- Fisher, C. M. et al., 2014. A benzimidazole functionalised DO3A chelator showing pH switchable coordination modes with lanthanide ions. Dalton Transactions 43 , pp.9567-9578. (10.1039/c4dt00519h)
- Gunnlaugsson, T. and Pope, S. J. 2014. Chapter 6: lanthanide ion complexes as chemosensors. In: Bettencourt-Dias, A. ed. Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials. Wiley-Blackwell. , pp.231. (10.1002/9781118682760.ch06)
- Hallett, A. J. et al. 2014. Silver nanoparticles functionalised with a luminescent iridium complex: phosphorescent hybrid materials. Transition Metal Chemistry 39 (2), pp.195-198. (10.1007/s11243-013-9789-2)
- Langdon-Jones, E. E. and Pope, S. J. A. 2014. The coordination chemistry of substituted anthraquinones: Developments and applications. Coordination Chemistry Reviews 269 , pp.32-53. (10.1016/j.ccr.2014.02.003)
- Langdon-Jones, E. E. et al. 2014. Fluorescent rhenium-naphthalimide conjugates as cellular imaging agents. Inorganic Chemistry 53 (7), pp.3788-3797. (10.1021/ic500142z)
- Langdon-Jones, E. E. and Pope, S. J. A. 2014. Recent developments in gold(i) coordination chemistry: luminescence properties and bioimaging opportunities. Chemical Communications- Royal Society of Chemistry 50 , pp.10343-10354. (10.1039/c4cc03259d)
- Palacios, M. A. et al., 2014. Bifunctional ZnIILnIII dinuclear complexes combining field induced SMM behavior and luminescence: enhanced NIR lanthanide emission by 9-anthracene carboxylate bridging ligands. Inorganic Chemistry 53 (3), pp.1465-1474. (10.1021/ic402597s)
- Regan, E. M. et al., 2014. A novel cobalt complex for enhancing amperometric and impedimetric DNA detection. Electrochimica Acta 128 , pp.10-15. (10.1016/j.electacta.2013.10.028)
- Ruiz, J. et al., 2014. Closely-related ZnII2LnIII2 complexes (LnIII = Gd, Yb) with either magnetic refrigerant or luminescent single-molecule magnet properties. Inorganic Chemistry 53 (7), pp.3586-3594. (10.1021/ic403097s)
- Taylor, R. G. D. et al., 2014. An organometallic complex revealing an unexpected, reversible, temperature induced SC-SC transformation. Crystengcomm 16 (21), pp.4641-4652. (10.1039/c4ce00070f)
2013
- Bennett, S. D. , Pope, S. J. A. and Ward, B. D. 2013. Near-IR luminescent neodymium complexes: spectroscopic probes for hydroamination catalysis. Chemical Communications 49 (54), pp.6072-6074. (10.1039/c3cc42923g)
- Cantos, P. M. , Pope, S. J. A. and Cahill, C. L. 2013. An exploration of homo- and heterometallic UO22+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies. CrystEngComm 15 (44), pp.9039-9051. (10.1039/c3ce41655k)
- El-Betany, A. M. et al. 2013. The synthesis and study of fluorescent PAMAM-based dendritic molecules. Tetrahedron 69 (39), pp.8439-8445. (10.1016/j.tet.2013.07.054)
- Langdon-Jones, E. E. et al. 2013. Using substituted cyclometalated quinoxaline ligands to finely tune the luminescence properties of iridium(III) complexes. Inorganic Chemistr 52 (1), pp.448-456. (10.1021/ic301853t)
- Mughal, S. et al. 2013. The tetratriptycenoporphyrazines revisited. Journal of Porphyrins and Phthalocyanines 17 (08n09), pp.778-784. (10.1142/S1088424613500351)
- Smith, R. A. et al. 2013. Cyclometalated cinchophen ligands on iridium(iii): towards water-soluble complexes with visible luminescence. Dalton Transactions 42 (28), pp.10347-10357. (10.1039/c3dt51098k)
- Stacey, O. J. and Pope, S. J. A. 2013. New avenues in the design and potential application of metal complexes for photodynamic therapy. RSC Advances 3 (48), pp.25550-25564. (10.1039/c3ra45219k)
- Thangavelu, S. G. et al., 2013. Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers. Inorganic Chemistry 52 (4), pp.2060-2069. (10.1021/ic3024698)
- Titos-Padilla, S. et al., 2013. Photophysical properties of [Ir(tpy)2]3+-doped silica nanoparticles and synthesis of a colour-tunable material based on an Ir(core)–Eu(shell) derivative. Journal of Materials Chemistry C 1 (24), pp.3808-3815. (10.1039/c3tc30466c)
2012
- Balasingham, R. et al. 2012. Gold(I) complexes derived from alkynyloxy-substituted anthraquinones: Syntheses, luminescence, preliminary cytotoxicity, and cell imaging studies. Organometallics 31 (16), pp.5835-5843. (10.1021/om300475y)
- Balasingham, R. G. et al. 2012. Biologically compatible, phosphorescent dimetallic rhenium complexes linked through functionalized alkyl chains: syntheses, spectroscopic properties, and applications in imaging microscopy. Inorganic Chemistry 51 (3), pp.1419-1426. (10.1021/ic201654d)
- Cox, N. M. et al., 2012. Probing solution behaviour of metallosupramolecular complexes using pyrene fluorescence. Dalton Transactions 41 (5), pp.1568-1573. (10.1039/c1dt11831e)
- Hallett, A. J. and Pope, S. J. 2012. First examples of luminescent zinc(II)-bisquinoxalinato complexes: synthesis, spectroscopic and theoretical studies. Inorganica Chimica Acta 387 , pp.145-150. (10.1016/j.ica.2012.01.008)
- Hallett, A. J. et al. 2012. Enhanced photooxidation sensitizers: the first examples of cyclometalated pyrene complexes of iridium(iii). Chemical Communications 48 (88), pp.10838-10840. (10.1039/c2cc35907c)
- Jones, J. E. et al. 2012. Water-soluble, luminescent iridium(III)–ytterbium(III) complexes using dipyrido[3,2-a:2′,3′-c]phenazine derivatives as bridging units. Dalton Transactions 41 (34), pp.10372-10381. (10.1039/c2dt31115a)
- Lloyd, D. , Coogan, M. P. and Pope, S. J. 2012. Novel metal-based luminophores for biological imaging. In: Geddes, C. D. ed. Reviews in Fluorescence 2010. Reviews in Fluorescence Vol. 7.New York: Springer. , pp.15-44. (10.1007/978-1-4419-9828-6_2)
- Mullice, L. A. et al. 2012. Gold(I) complexes incorporating emissive mercapto-pteridine ligands: Syntheses, X-ray structure, luminescence and preliminary cytotoxic evaluation. European Journal of Inorganic Chemistry 2012 (18), pp.3054-3060. (10.1002/ejic.201200147)
- Routledge, J. D. et al. 2012. Tuning the electronics of phosphorescent, amide-functionalized, cyclometalated IrIII complexes: Syntheses, structures, spectroscopy and theoretical Studies. European Journal of Inorganic Chemistry 2012 (25), pp.4065-4075. (10.1002/ejic.201200647)
2011
- Andrews, M. et al. 2011. Luminescent probes based on water-soluble, dual-emissive lanthanide complexes: metal ion-induced modulation of near-IR emission. Chemical Communications 47 (1), pp.206-208. (10.1039/c0cc00210k)
- Andrews, M. , Kariuki, B. and Pope, S. J. A. 2011. Functional luminescent lanthanide complexes: modulation of visible luminescence from europium complexes. Polyhedron 30 (12), pp.2055-2061. (10.1016/j.poly.2011.05.008)
- Carcedo, C. et al. 2011. Chiral silver and gold rings: synthesis and structural, spectroscopic, and photophysical properties of Ag and Au metallamacrocycles of bridging NHC ligands. Organometallics 30 (9), pp.2553-2562. (10.1021/om200125w)
- Hallett, A. J. , Kariuki, B. and Pope, S. J. A. 2011. New 2,3-disubstituted-5-hydroxyquinoxaline ligands and their coordination chemistry with cyclometallated iridium(iii): syntheses, structures and tunable electronic properties. Dalton Transactions 40 (37), pp.9474-9481. (10.1039/c1dt10707k)
- Hallett, A. J. and Pope, S. J. A. 2011. Towards near-IR emissive rhenium tricarbonyl complexes: Synthesis and characterisation of unusual 2,2'-biquinoline complexes. Inorganic Chemistry Communications 14 (10), pp.1606-1608. (10.1016/j.inoche.2011.06.021)
- Hardwick, H. C. et al., 2011. Structural, spectroscopic and redox properties of uranyl complexes with a maleonitrile containing ligand. Dalton Transactions 40 (22), pp.5939-5952. (10.1039/c0dt01580f)
- Jones, J. E. et al. 2011. Bimodal, dimetallic lanthanide complexes that bind to DNA: the nature of binding and its influence on water relaxivity. Chemical Communications 47 (12), pp.3374-3376. (10.1039/C1CC00111F)
- Jones, J. E. et al. 2011. Amino-anthraquinone chromophores functionalised with 3-picolyl units: structures, luminescence, DFT and their coordination chemistry with cationic Re(I) di-imine complexes. Dalton Transactions 40 (14), pp.3498-3509. (10.1039/C0DT01383H)
2010
- Andrews, M. et al., 2010. Responsive, di-metallic lanthanide complexes of a piperazine-bridged bis-macrocyclic ligand: modulation of visible luminescence and proton relaxivity. Dalton Transactions 39 (14), pp.3407-3411. (10.1039/b923988j)
- Bagley, M. C. , Lin, Z. and Pope, S. J. A. 2010. Microwave-assisted synthesis and complexation of luminescent cyanobipyridyl-zinc(ii) bis(thiolate) complexes with intrinsic and ancillary photophysical tunability. Dalton Transactions 39 (13), pp.3163-3166. (10.1039/c001898h)
- Coogan, M. P. et al. 2010. Probing intracellular oxygen by quenched phosphorescence lifetimes of nanoparticles containing polyacrylamide-embedded [Ru(dpp(SO3Na)2)3]Cl2. Photochemical and Photobiological Sciences 9 (1), pp.103-109. (10.1039/b9pp00071b)
- Hallett, A. J. et al. 2010. Neutral and cationic cyclometallated Ir(III) complexes of anthra[1,2-d]-imidazole-6,11-dione-derived ligands: Syntheses, structures and spectroscopic characterisation. Journal of Organometallic Chemistry 695 (22), pp.2401-2409. (10.1016/j.jorganchem.2010.07.017)
- Knighton, R. C. et al. 2010. A one-step synthesis towards new ligands based on aryl-functionalised thiazolo[5,4-d]thiazole chromophores. Tetrahedron Letters 51 (41), pp.5419-5422. (10.1016/j.tetlet.2010.07.172)
- Mullice, L. and Pope, S. J. A. 2010. The development of responsive, luminescent lifetime probes based upon axially functionalised fac-[Re(CO)3(di-imine)(L)]+ complexes. Dalton Transactions 39 (25), pp.5908-5917. (10.1039/c0dt00109k)
- Perry, W. S. et al., 2010. Synthesis and photophysical properties of kinetically stable complexes containing a lanthanide ion and a transition metal antenna group. Dalton Transactions 39 (45), pp.10974-10983. (10.1039/c0dt00877j)
- Yeo, B. R. et al. 2010. The Re(I) coordination chemistry of a series of pyrido[2,3-b]pyrazine-derived ligands: Syntheses, characterisation and crystal structures. Polyhedron 29 (3), pp.1088-1094. (10.1016/j.poly.2009.11.013)
2009
- Andrews, M. B. , Laye, R. H. and Pope, S. J. A. 2009. A luminescent rhenium(I) complex of 2,7-dimethyl-1,8-naphthyridine: synthesis, spectroscopy and X-ray crystal structure. Transition Metal Chemistry 34 (5), pp.493-497. (10.1007/s11243-009-9221-0)
- Andrews, M. B. et al. 2009. Sensitized Lanthanide-Ion Luminescence with Aryl-Substituted N-(2-Nitrophenyl)acetamide-Derived Chromophores. Helvetica Chimica Acta 92 (11), pp.2159-2172. (10.1002/hlca.200900108)
- Bagley, M. C. , Lin, Z. F. and Pope, S. J. A. 2009. Rapid synthesis of 3-cyanopyridine-derived chromophores with two-dimensional tunability and solvatochromic photophysical properties. Chemical Communications (34), pp.5165-5167. (10.1039/b910664b)
- Bagley, M. C. , Lin, Z. and Pope, S. J. A. 2009. Barium manganate in microwave-assisted oxidation reactions: synthesis of solvatochromic 2,4,6-triarylpyrimidines. Tetrahedron Letters 50 (49), pp.6818-6822. (10.1016/j.tetlet.2009.09.116)
- Bullock, S. J. et al., 2009. Coumarin-based luminescent ligand that forms helicates with dicationic metal ions. Dalton Transactions (47), pp.10570-10573. (10.1039/b913103e)
- Coogan, M. P. et al. 2009. Rhenium fac-tricarbonyl bisimine complexes: luminescence modulation by hydrophobically driven intramolecular interactions. New Journal of Chemistry 33 (5), pp.1094-1099. (10.1039/b819453j)
- Coogan, M. P. et al. 2009. A rhenium tricarbonyl 4'-oxo-terpy trimer as a luminescent molecular vessel with a removable silver stopper. Angewandte Chemie - International Edition 48 (27), pp.4965-4968. (10.1002/anie.200900981)
- Hallett, A. J. et al. 2009. Luminescent, water-soluble gold nanoparticles functionalised with 3MLCT emitting rhenium complexes. Chemical Communications (28), pp.4278-4280. (10.1039/b905692k)
- Jones, J. E. and Pope, S. J. A. 2009. Sensitised near-IR lanthanide luminescence exploiting anthraquinone-derived chromophores: syntheses and spectroscopic properties. Dalton Transactions (39), pp.8421-8425. (10.1039/b913902h)
- Mullice, L. A. et al. 2009. The coordination chemistry of fluorescent pyridinyl- and quinolinyl-phthalimide ligands with the {Au-I-PPh3} cationic unit. Dalton Transactions (34), pp.6836-6842. (10.1039/b905123f)
- Thorp-Greenwood, F. L. et al. 2009. Syntheses, structural studies and spectroscopic characterisation of pyridyl-phthalimide complexes of fac-(CO)(3)Re-I-diimines. Journal of Organometallic Chemistry 694 (9-10), pp.1400-1406. (10.1016/j.jorganchem.2008.12.048)
2008
- Amoroso, A. J. et al. 2008. 3-Chloromethylpyridyl bipyridine fac-tricarbonyl rhenium: a thiol-reactive luminophore for fluorescence microscopy accumulates in mitochondria. New Journal of Chemistry 32 (7), pp.1097-1102. (10.1039/b802215a)
- Andrews, M. B. et al. 2008. Quinoxaline sensitised lanthanide ion luminescence: Syntheses, spectroscopy and X-ray crystal structure of Na{1,4,7-tris[(N-diethyl)carbamoylmethyl]-1,4,7,10-tetraazacyclododecane -10-(2-methylquinoxaline)}I-3 C7H8. Polyhedron 27 (11), pp.2365-2371. (10.1016/j.poly.2008.04.010)
- Baca, S. G. et al., 2008. Cyanide-bridged Os(II)/Ln(III) coordination networks containing [Os(phen)(CN)(4)](2-) as an energy donor: Structural and photophysical properties. Inorganic Chemistry 47 (9), pp.3736-3747. (10.1021/ic702353c)
- Felton, C. E. et al., 2008. A wavelength and lifetime responsive cryptate-containing fluorescent probe for zinc ions in water. Chemical Communications 2008 (46), pp.6185-6187. (10.1039/b813775g)
- Koullourou, T. et al., 2008. Synthesis and spectroscopic properties of a prototype single molecule dual imaging agent comprising a heterobimetallic rhenium-gadolinium complex. Journal of the American Chemical Society 130 (7), pp.2178-2179. (10.1021/ja710859p)
- Mullice, L. A. et al. 2008. Rhenium complexes of chromophore-appended dipicolylamine ligands: syntheses, spectroscopic properties, DNA binding and X-ray crystal structure. New Journal of Chemistry 32 (12), pp.2140-2149. (10.1039/b800999f)
2007
- Adams, C. J. et al., 2007. Synthesis, structures and properties of a new series of platinum-diimine-dithiolate complexes. Dalton Transactions 2007 (39), pp.4446-4456. (10.1039/b709252k)
- Amoroso, A. J. et al. 2007. Rhenium fac tricarbonyl bisimine complexes: biologically useful fluorochromes for cell imaging applications. Chemical Communications (29), pp.3066-3068. (10.1039/b706657k)
- Herrera, J. et al., 2007. Photophysical and Structural Properties of Cyanoruthenate Complexes of Hexaazatriphenylene. Journal of the American Chemical Society 129 (37), pp.11491-11504. (10.1021/ja072672w)
- Lazarides, T. et al., 2007. Anthracene as a sensitiser for near-infrared luminescence in complexes of Nd(iii), Er(iii) and Yb(iii): an unexpected sensitisation mechanism based on electron transfer. Dalton Transactions 2007 (15), pp.1484-1491. (10.1039/b700714k)
- Lazarides, T. et al., 2007. Ligand-field excited states of hexacyanochromate and hexacyanocobaltate as sensitisers for near-infrared luminescence from Nd(III) and Yb(III) in cyanide-bridged d–f assemblies. Photochemical & Photobiological Sciences 6 (11), pp.1152-1157. (10.1039/b708683k)
- Pope, S. J. A. 2007. Dual-emissive complexes: Visible and near-infrared luminescence from bis-pyrenyl lanthanide(III) complexes. Polyhedron 26 (17), pp.4818-4824. (10.1016/j.poly.2007.06.036)
- Ronson, T. K. et al., 2007. Polynuclear lanthanide complexes of a series of bridging ligands containing two tridentate N,N′,O-donor units: structures and luminescence properties. Dalton Transactions 2007 (10), pp.1006-1022. (10.1039/b618258e)
- Talbot-Eeckelaers, C. et al., 2007. Luminescence from Neptunyl(VI) Species in Solution. Journal of the American Chemical Society 129 (9), pp.2442-2443. (10.1021/ja068522n)
2006
- Herrera, J. et al., 2006. Structural and Photophysical Properties of Coordination Networks Combining [Ru(Bpym)(CN)4]2- or [{Ru(CN)4}2(μ-bpym)]4- Anions (bpym = 2,2‘-Bipyrimidine) with Lanthanide(III) Cations: Sensitized Near-Infrared Luminescence from Yb(III), Nd(III), and Er(III) Following Ru-to-Lanthanide Energy Transfer. Inorganic Chemistry 45 (10), pp.3895-3904. (10.1021/ic0521574)
- Herrera, J. et al., 2006. Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties. Chemical Communications 2006 (17), pp.1851-1853. (10.1039/b601876a)
- Pope, S. J. A. et al. 2006. Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(iii) complexes and chromophore bearing carboxylates and phosphonates. Dalton Transactions 2006 (23), pp.2907-2912. (10.1039/b600598e)
- Pope, S. J. A. and Laye, R. H. 2006. Design, synthesis and photophysical studies of an emissive, europium based, sensor for zinc. Dalton Transactions (25), pp.3108-3113. (10.1039/b605837j)
- Ronson, T. K. et al., 2006. Luminescent PtII(bipyridyl)(diacetylide) Chromophores with Pendant Binding Sites as Energy Donors for Sensitised Near-Infrared Emission from Lanthanides: Structures and Photophysics of PtII/LnIII Assemblies. Chemistry - a European Journal 12 (36), pp.9299-9313. (10.1002/chem.200600698)
- Sambrook, M. R. et al., 2006. Sensitised near infrared emission from lanthanides via anion-templated assembly of d–f heteronuclear [2]pseudorotaxanes [Letter]. New Journal of Chemistry 30 (8), pp.1133-1136. (10.1039/b601017b)
- Sénéchal-David, K. et al., 2006. Sensitized Near-Infrared Lanthanide Luminescence from Nd(III)- and Yb(III)-Based Cyclen−Ruthenium Coordination Conjugates. Inorganic Chemistry 45 (25), pp.10040-10042. (10.1021/ic061706i)
2005
- Bichenkova, E. V. et al., 2005. DNA Mismatch Detection by Resonance Energy Transfer between Ruthenium(II) and Osmium(II) Tris(2,2‘-bipyridyl) Chromophores. Inorganic Chemistry 44 (12), pp.4112-4114. (10.1021/ic050586w)
- Davies, G. M. et al., 2005. Photophysical properties of Pr(iii) and Er(iii) complexes of poly(pyrazolyl)borates. Photochemical & Photobiological Sciences 4 (10), pp.829-834. (10.1039/b508382f)
- Davies, G. M. et al., 2005. Structural and Photophysical Properties of Coordination Networks Combining [Ru(bipy)(CN)4]2-Anions and Lanthanide(III) Cations: Rates of Photoinduced Ru-to-Lanthanide Energy Transfer and Sensitized Near-Infrared Luminescence. Inorganic Chemistry 44 (13), pp.4656-4665. (10.1021/ic050512k)
- Faulkner, S. , Pope, S. J. A. and Burton-Pye, B. P. 2005. Lanthanide Complexes for Luminescence Imaging Applications. Applied Spectroscopy Reviews 40 (1), pp.1-31. (10.1081/ASR-200038308)
- González-Lorenzo, M. et al., 2005. Structural and Photophysical Properties of Lathanide(III) Complexes with a Novel Octadentate Iminophenolate Bibracchial Lariat Ether. Inorganic Chemistry 44 (12), pp.4254-4262. (10.1021/ic048172a)
- Pope, S. J. A. et al. 2005. Metal-to-ligand charge-transfer sensitisation of near-infrared emitting lanthanides in trimetallic arrays M2Ln (M = Ru, Re or Os; Ln = Nd, Er or Yb). Dalton Transactions 2005 (8), pp.1482-1490. (10.1039/b500849b)
2004
- Adams, C. J. and Pope, S. J. A. 2004. Diimine-Acetylide Compounds of Ruthenium: The Structural and Spectroscopic Effects of Oxidation. Inorganic Chemistry 43 (11), pp.3492-3499. (10.1021/ic035181v)
- Faulkner, S. et al., 2004. Pyrene-sensitised near-IR luminescence from ytterbium and neodymium complexes. Dalton Transactions 2004 (9), pp.1405-1409. (10.1039/b401302f)
- Miller, T. A. et al., 2004. Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(III) units. Dalton Transactions 2004 (10), pp.1524-1526. (10.1039/b404820b)
- Pope, S. J. A. , Coe, B. J. and Faulkner, S. 2004. Re(i) sensitised near-infrared lanthanide luminescence from a hetero-trinuclear Re2Ln array. Chemical Communications 2004 (13), pp.1550-1551. (10.1039/b402270j)
- Pope, S. J. A. et al. 2004. Self-Assembly of Heterobimetallic d-f Hybrid Complexes: Sensitization of Lanthanide Luminescence by d-Block Metal-to-Ligand Charge-Transfer Excited States. Journal of the American Chemical Society 126 (31), pp.9490-9491. (10.1021/ja047523h)
2003
- Faulkner, S. and Pope, S. J. A. 2003. Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex. Journal of the American Chemical Society 125 (35), pp.10526-10527. (10.1021/ja035634v)
- Pope, S. J. A. et al. 2003. Synthesis and luminescence properties of a kinetically stable dinuclear ytterbium complex with differentiated binding sites. Chemical Communications 2003 (13), pp.1550-1551. (10.1039/b303012a)
- Pope, S. J. A. et al. 2003. Synthesis and luminescence properties of dinuclear lanthanide complexes derived from covalently linked macrocyclic ligands. Dalton Transactions 2003 (19), pp.3780-3784. (10.1039/b309115e)
- Shavaleev, N. M. et al., 2003. Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(ii) fragment as an antenna group. Chemical Communications 2003 (10), pp.1134-1135. (10.1039/b301878d)
- Shavaleev, N. M. et al., 2003. Sensitized Near-Infrared Emission from Complexes of YbIII, NdIII and ErIII by Energy-Transfer from Covalently Attached PtII-Based Antenna Units. Chemistry - a European Journal 9 (21), pp.5283-5291. (10.1002/chem.200305132)
- Shavaleev, N. M. et al., 2003. Visible-light sensitisation of near-infrared luminescence from Yb(iii), Nd(iii) and Er(iii) complexes of 3,6-bis(2-pyridyl)tetrazine. Dalton Transactions 2003 (5), pp.808-814. (10.1039/b300294b)
2002
- Morales, A. F. et al., 2002. Interplay of Light Antenna and Excitation “Energy Reservoir” Effects in a Bichromophoric System Based on Ruthenium−Polypyridine and Pyrene Units Linked by a Long and Flexible Poly(ethylene glycol) Chain. Inorganic Chemistry 41 (25), pp.6711-6719. (10.1021/ic025811d)
2001
- Pope, S. J. A. et al. 2001. Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini. Journal of the Chemical Society, Dalton Transactions 2001 (15), pp.2228-2231. (10.1039/b104637n)
2000
- Heuer, B. , Pope, S. J. A. and Reid, G. 2000. Synthesis, spectroscopic and structural characterisation of copper, silver and gold complexes of the mixed P/O-donor ligand Ph2P(CH2)2O(CH2)2O(CH2)2PPh2. Polyhedron 19 (7), pp.743-749. (10.1016/S0277-5387(00)00291-6)
1999
- Campbell, T. et al., 1999. Synthesis, spectroscopic and structural characterisation of chromium(0), molybdenum(0) and tungsten(0) complexes involving primary and secondary phosphines. Journal of Organometallic Chemistry 592 (2), pp.296-305. (10.1016/S0022-328X(99)00570-7)
- Connolly, J. et al., 1999. Co(III) and Cr(III) complexes of diphosphadithia ligands and the crystal structure of [CoCl2(L3)]PF6·CH2Cl2 (L3=Ph2P(CH2)2S(o-C6H4)S(CH2)2PPh2). Polyhedron 18 (26), pp.3553-3558. (10.1016/S0277-5387(99)00285-5)
- Connolly, J. et al., 1999. Cationic manganese(I) tricarbonyl complexes with group 15 and 16 donor ligands: synthesis, multinuclear NMR spectroscopy and crystal structures. Journal of the Chemical Society. Dalton Transactions 1999 (14), pp.2343-2352. (10.1039/a902820j)
- Pope, S. J. A. and Reid, G. 1999. Phosphine, arsine and stibine complexes of manganese(I) carbonyl halides: synthesis, multinuclear NMR spectroscopic studies, redox properties and crystal structures. Journal of the Chemical Society. Dalton Transactions 1999 (10), pp.1615-1622. (10.1039/a900875f)
1998
- Connolly, J. et al., 1998. Pd(II) and Pt(II) complexes with chalcogenide derivatized phosphathia ligands. Polyhedron 17 (13-14), pp.2331-2336. (10.1016/S0277-5387(97)00508-1)
- Davies, S. C. et al., 1998. Synthesis, spectroscopic and EXAFS studies of vanadium complexes of trithioether ligands and crystal structures of [VCl3([9]aneS3)] and [VI2(thf )([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane). Journal of the Chemical Society. Dalton Transactions 1998 (13), pp.2191-2198. (10.1039/a802404i)
- Patel, B. , Pope, S. J. A. and Reid, G. 1998. Rhodium complexes with secondary phosphine and phosphinite ligands and the crystal structures of [(PPh2OH)2(PPh2O)Rh(μ-Cl)3Rh(PPh2OH)(PPh2O)2] and [(PPh2OH)(PPh2O)Cl(NCMe)Rh(μ-Cl)2Rh(PPh2OH)(PPh2O)Cl(NCMe)] · 2thf. Polyhedron 17 (13-14), pp.2345-2351. (10.1016/S0277-5387(97)00460-9)
1995
- Pope, S. J. A. and West, Y. D. 1995. Comparison of the FT Raman spectra of inorganic tetrahedral ions over the temperature range 77 to 473 K. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51 (12), pp.2027-2037. (10.1016/0584-8539(95)01509-1)
- Pope, S. J. A. and West, Y. D. 1995. Use of the FT Raman spectrum of Na2MoO4 to study sample heating by the laser. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51 (12), pp.2011-2017. (10.1016/0584-8539(95)01470-X)
Articles
- Adams, C. J. et al., 2007. Synthesis, structures and properties of a new series of platinum-diimine-dithiolate complexes. Dalton Transactions 2007 (39), pp.4446-4456. (10.1039/b709252k)
- Adams, C. J. and Pope, S. J. A. 2004. Diimine-Acetylide Compounds of Ruthenium: The Structural and Spectroscopic Effects of Oxidation. Inorganic Chemistry 43 (11), pp.3492-3499. (10.1021/ic035181v)
- Al-Riyahee, A. A. A. et al. 2022. N,N′-Substituted thioureas and their metal complexes: syntheses, structures and electronic properties. Dalton Transactions 51 (9), pp.3531-3545. (10.1039/D1DT04091J)
- Al-Riyahee, A. A. et al., 2022. Ni(II), Cu(II) and Zn(II) complexes of functionalised thiosemicarbazone ligands: Syntheses and reactivity, characterization and structural studies. Polyhedron 225 116079. (10.1016/j.poly.2022.116079)
- Al-Riyahee, A. A. et al. 2019. Syntheses, X-ray structures and characterisation of luminescent chromium(III) complexes incorporating 8-quinolinato ligands. Polyhedron 157 , pp.396. (10.1016/j.poly.2018.10.019)
- Alkhaibari, I. et al. 2025. DNA‐binding properties of non‐intercalating water‐soluble organometallic Ir(III) luminophores. Chemistry - A European Journal 31 (30) e202500290. (10.1002/chem.202500290)
- Alkhaibari, I. S. et al. 2024. Tuning excited state character in iridium(III) photosensitizers and its influence on TTA-UC. Inorganic Chemistry 63 (21), pp.9931-9940. (10.1021/acs.inorgchem.4c01003)
- Amoroso, A. J. et al. 2008. 3-Chloromethylpyridyl bipyridine fac-tricarbonyl rhenium: a thiol-reactive luminophore for fluorescence microscopy accumulates in mitochondria. New Journal of Chemistry 32 (7), pp.1097-1102. (10.1039/b802215a)
- Amoroso, A. J. et al. 2007. Rhenium fac tricarbonyl bisimine complexes: biologically useful fluorochromes for cell imaging applications. Chemical Communications (29), pp.3066-3068. (10.1039/b706657k)
- Amoroso, A. J. , Fallis, I. A. and Pope, S. J. A. 2017. Chelating agents for radiolanthanides: applications to imaging and therapy. Coordination Chemistry Reviews 340 , pp.198-219. (10.1016/j.ccr.2017.01.010)
- Amoroso, A. J. and Pope, S. J. A. 2015. Using lanthanide ions in molecular bioimaging. Chemical Society Reviews 44 (14), pp.4723-4742. (10.1039/C4CS00293H)
- Andrews, M. et al., 2010. Responsive, di-metallic lanthanide complexes of a piperazine-bridged bis-macrocyclic ligand: modulation of visible luminescence and proton relaxivity. Dalton Transactions 39 (14), pp.3407-3411. (10.1039/b923988j)
- Andrews, M. et al. 2011. Luminescent probes based on water-soluble, dual-emissive lanthanide complexes: metal ion-induced modulation of near-IR emission. Chemical Communications 47 (1), pp.206-208. (10.1039/c0cc00210k)
- Andrews, M. , Kariuki, B. and Pope, S. J. A. 2011. Functional luminescent lanthanide complexes: modulation of visible luminescence from europium complexes. Polyhedron 30 (12), pp.2055-2061. (10.1016/j.poly.2011.05.008)
- Andrews, M. B. et al. 2008. Quinoxaline sensitised lanthanide ion luminescence: Syntheses, spectroscopy and X-ray crystal structure of Na{1,4,7-tris[(N-diethyl)carbamoylmethyl]-1,4,7,10-tetraazacyclododecane -10-(2-methylquinoxaline)}I-3 C7H8. Polyhedron 27 (11), pp.2365-2371. (10.1016/j.poly.2008.04.010)
- Andrews, M. B. , Laye, R. H. and Pope, S. J. A. 2009. A luminescent rhenium(I) complex of 2,7-dimethyl-1,8-naphthyridine: synthesis, spectroscopy and X-ray crystal structure. Transition Metal Chemistry 34 (5), pp.493-497. (10.1007/s11243-009-9221-0)
- Andrews, M. B. et al. 2009. Sensitized Lanthanide-Ion Luminescence with Aryl-Substituted N-(2-Nitrophenyl)acetamide-Derived Chromophores. Helvetica Chimica Acta 92 (11), pp.2159-2172. (10.1002/hlca.200900108)
- Baca, S. G. et al., 2008. Cyanide-bridged Os(II)/Ln(III) coordination networks containing [Os(phen)(CN)(4)](2-) as an energy donor: Structural and photophysical properties. Inorganic Chemistry 47 (9), pp.3736-3747. (10.1021/ic702353c)
- Bagley, M. C. , Lin, Z. F. and Pope, S. J. A. 2009. Rapid synthesis of 3-cyanopyridine-derived chromophores with two-dimensional tunability and solvatochromic photophysical properties. Chemical Communications (34), pp.5165-5167. (10.1039/b910664b)
- Bagley, M. C. , Lin, Z. and Pope, S. J. A. 2009. Barium manganate in microwave-assisted oxidation reactions: synthesis of solvatochromic 2,4,6-triarylpyrimidines. Tetrahedron Letters 50 (49), pp.6818-6822. (10.1016/j.tetlet.2009.09.116)
- Bagley, M. C. , Lin, Z. and Pope, S. J. A. 2010. Microwave-assisted synthesis and complexation of luminescent cyanobipyridyl-zinc(ii) bis(thiolate) complexes with intrinsic and ancillary photophysical tunability. Dalton Transactions 39 (13), pp.3163-3166. (10.1039/c001898h)
- Balasingham, R. et al. 2012. Gold(I) complexes derived from alkynyloxy-substituted anthraquinones: Syntheses, luminescence, preliminary cytotoxicity, and cell imaging studies. Organometallics 31 (16), pp.5835-5843. (10.1021/om300475y)
- Balasingham, R. G. et al. 2012. Biologically compatible, phosphorescent dimetallic rhenium complexes linked through functionalized alkyl chains: syntheses, spectroscopic properties, and applications in imaging microscopy. Inorganic Chemistry 51 (3), pp.1419-1426. (10.1021/ic201654d)
- Bennett, S. D. et al., 2016. Scandium complexes bearing bis(oxazolinylphenyl)amide ligands: an analysis of their reactivity, solution-state structures and photophysical properties. European Journal of Inorganic Chemistry 2016 (18), pp.2932-2941. (10.1002/ejic.201600223)
- Bennett, S. D. et al. 2014. Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. Dalton Transactions 43 (15), pp.5871-5885. (10.1039/c4dt00114a)
- Bennett, S. D. , Pope, S. J. A. and Ward, B. D. 2013. Near-IR luminescent neodymium complexes: spectroscopic probes for hydroamination catalysis. Chemical Communications 49 (54), pp.6072-6074. (10.1039/c3cc42923g)
- Bichenkova, E. V. et al., 2005. DNA Mismatch Detection by Resonance Energy Transfer between Ruthenium(II) and Osmium(II) Tris(2,2‘-bipyridyl) Chromophores. Inorganic Chemistry 44 (12), pp.4112-4114. (10.1021/ic050586w)
- Bonello, R. O. et al., 2017. Synthesis and characterisation of phosphorescent rhenium(I) complexes of hydroxy- and methoxy-substituted imidazo[4,5- f ]-1,10-phenanthroline ligands. Journal of Organometallic Chemistry 841 , pp.39-47. (10.1016/j.jorganchem.2017.04.021)
- Bonello, R. O. et al. 2022. Aryl, bi-functionalised imidazo[4,5-f]-1,10-phenanthroline ligands and their luminescent rhenium(I) complexes. Polyhedron 228 116179. (10.1016/j.poly.2022.116179)
- Bonello, R. O. et al. 2014. Luminescent rhenium(I) complexes of substituted imidazole[4,5-f]-1,10-phenanthroline derivatives. Journal of Organometallic Chemistry 749 , pp.150-156. (10.1016/j.jorganchem.2013.08.031)
- Bullock, S. J. et al., 2009. Coumarin-based luminescent ligand that forms helicates with dicationic metal ions. Dalton Transactions (47), pp.10570-10573. (10.1039/b913103e)
- Campbell, T. et al., 1999. Synthesis, spectroscopic and structural characterisation of chromium(0), molybdenum(0) and tungsten(0) complexes involving primary and secondary phosphines. Journal of Organometallic Chemistry 592 (2), pp.296-305. (10.1016/S0022-328X(99)00570-7)
- Cantos, P. M. , Pope, S. J. A. and Cahill, C. L. 2013. An exploration of homo- and heterometallic UO22+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies. CrystEngComm 15 (44), pp.9039-9051. (10.1039/c3ce41655k)
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- Pope, S. J. A. et al. 2017. Anticancer, azonafide-inspired fluorescent ligands and their rhenium(I) complexes for cellular imaging. European Journal of Inorganic Chemistry 2017 (3), pp.759-766. (10.1002/ejic.201601271)
- Pope, S. J. A. and Laye, R. H. 2006. Design, synthesis and photophysical studies of an emissive, europium based, sensor for zinc. Dalton Transactions (25), pp.3108-3113. (10.1039/b605837j)
- Pope, S. J. A. and Reid, G. 1999. Phosphine, arsine and stibine complexes of manganese(I) carbonyl halides: synthesis, multinuclear NMR spectroscopic studies, redox properties and crystal structures. Journal of the Chemical Society. Dalton Transactions 1999 (10), pp.1615-1622. (10.1039/a900875f)
- Pope, S. J. A. et al. 2001. Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini. Journal of the Chemical Society, Dalton Transactions 2001 (15), pp.2228-2231. (10.1039/b104637n)
- Pope, S. J. A. and West, Y. D. 1995. Comparison of the FT Raman spectra of inorganic tetrahedral ions over the temperature range 77 to 473 K. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51 (12), pp.2027-2037. (10.1016/0584-8539(95)01509-1)
- Pope, S. J. A. and West, Y. D. 1995. Use of the FT Raman spectrum of Na2MoO4 to study sample heating by the laser. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51 (12), pp.2011-2017. (10.1016/0584-8539(95)01470-X)
- Rainbow, J. et al., 2025. Electrochemical signal amplification for pathogen nucleic acid detection utilizing a cobalt-based DNA-binding metallo-intercalator. Sensors & Diagnostics 4 (6), pp.519-528. (10.1039/D4SD00322E)
- Regan, E. M. et al., 2014. A novel cobalt complex for enhancing amperometric and impedimetric DNA detection. Electrochimica Acta 128 , pp.10-15. (10.1016/j.electacta.2013.10.028)
- Ronson, T. K. et al., 2007. Polynuclear lanthanide complexes of a series of bridging ligands containing two tridentate N,N′,O-donor units: structures and luminescence properties. Dalton Transactions 2007 (10), pp.1006-1022. (10.1039/b618258e)
- Ronson, T. K. et al., 2006. Luminescent PtII(bipyridyl)(diacetylide) Chromophores with Pendant Binding Sites as Energy Donors for Sensitised Near-Infrared Emission from Lanthanides: Structures and Photophysics of PtII/LnIII Assemblies. Chemistry - a European Journal 12 (36), pp.9299-9313. (10.1002/chem.200600698)
- Routledge, J. D. et al. 2012. Tuning the electronics of phosphorescent, amide-functionalized, cyclometalated IrIII complexes: Syntheses, structures, spectroscopy and theoretical Studies. European Journal of Inorganic Chemistry 2012 (25), pp.4065-4075. (10.1002/ejic.201200647)
- Ruiz, J. et al., 2014. Closely-related ZnII2LnIII2 complexes (LnIII = Gd, Yb) with either magnetic refrigerant or luminescent single-molecule magnet properties. Inorganic Chemistry 53 (7), pp.3586-3594. (10.1021/ic403097s)
- Sambrook, M. R. et al., 2006. Sensitised near infrared emission from lanthanides via anion-templated assembly of d–f heteronuclear [2]pseudorotaxanes [Letter]. New Journal of Chemistry 30 (8), pp.1133-1136. (10.1039/b601017b)
- Sawicka, N. et al. 2022. Long-lived, near-IR emission from Cr(iii) under ambient conditions. Chemical Communications 58 (38), pp.5733-5736. (10.1039/D2CC01434C)
- Sénéchal-David, K. et al., 2006. Sensitized Near-Infrared Lanthanide Luminescence from Nd(III)- and Yb(III)-Based Cyclen−Ruthenium Coordination Conjugates. Inorganic Chemistry 45 (25), pp.10040-10042. (10.1021/ic061706i)
- Shavaleev, N. M. et al., 2003. Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(ii) fragment as an antenna group. Chemical Communications 2003 (10), pp.1134-1135. (10.1039/b301878d)
- Shavaleev, N. M. et al., 2003. Sensitized Near-Infrared Emission from Complexes of YbIII, NdIII and ErIII by Energy-Transfer from Covalently Attached PtII-Based Antenna Units. Chemistry - a European Journal 9 (21), pp.5283-5291. (10.1002/chem.200305132)
- Shavaleev, N. M. et al., 2003. Visible-light sensitisation of near-infrared luminescence from Yb(iii), Nd(iii) and Er(iii) complexes of 3,6-bis(2-pyridyl)tetrazine. Dalton Transactions 2003 (5), pp.808-814. (10.1039/b300294b)
- Smith, R. A. et al. 2013. Cyclometalated cinchophen ligands on iridium(iii): towards water-soluble complexes with visible luminescence. Dalton Transactions 42 (28), pp.10347-10357. (10.1039/c3dt51098k)
- Soltani, Y. et al. 2018. Synthesis and photophysical properties of imine borane adducts towards vapochromic materials. Dalton Transactions 47 (36), pp.12656-12660. (10.1039/C8DT03019G)
- Spencer, J. et al. 2020. CW EPR investigation of red-emitting CaS:Eu phosphors: rationalization of local electronic structure. Advanced Optical Materials 8 (22) 2001241. (10.1002/adom.202001241)
- Stacey, O. J. et al. 2015. Water soluble, cyclometalated Pt(II)–Ln(III) conjugates towards novel bimodal imaging agents. Chemical Communications 51 (61), pp.12305-12308. (10.1039/C5CC02623G)
- Stacey, O. J. et al. 2015. Phosphorescent, cyclometalated cinchophen-derived platinum complexes: syntheses, structures, and electronic properties. Inorganic Chemistry 150619121705005. (10.1021/acs.inorgchem.5b00817)
- Stacey, O. J. and Pope, S. J. A. 2013. New avenues in the design and potential application of metal complexes for photodynamic therapy. RSC Advances 3 (48), pp.25550-25564. (10.1039/c3ra45219k)
- Stacey, O. J. et al., 2016. Chromophore-labelled, luminescent platinum complexes: syntheses, structures, and spectroscopic properties. Dalton Transactions 45 , pp.10297-10307. (10.1039/C6DT01335J)
- Stacey, O. J. et al., 2016. Near-IR luminescent lanthanide complexes with 1,8-diaminoanthraquinone-based chromophoric ligands. Dalton Transactions 45 (15), pp.6674-6681. (10.1039/C5DT04351D)
- Stokes, E. C. et al. 2015. Cationic, luminescent cyclometalated iridium(iii) complexes based on substituted 2-phenylthiazole ligands. Dalton Transactions 44 (18), pp.8488-8496. (10.1039/C4DT03054K)
- Stokes, E. C. et al. 2024. Alkyl chain functionalised Ir(iii) complexes: synthesis, properties and behaviour as emissive dopants in microemulsions. RSC Advances 14 (10), pp.6987-6997. (10.1039/D3RA06764E)
- Stonelake, T. M. et al. 2020. Spectroscopic and theoretical investigation of color tuning in deep-red luminescent iridium(III) complexes. Inorganic Chemistry 59 (4)(10.1021/acs.inorgchem.9b02991)
- Talbot-Eeckelaers, C. et al., 2007. Luminescence from Neptunyl(VI) Species in Solution. Journal of the American Chemical Society 129 (9), pp.2442-2443. (10.1021/ja068522n)
- Taylor, R. G. D. et al., 2014. An organometallic complex revealing an unexpected, reversible, temperature induced SC-SC transformation. Crystengcomm 16 (21), pp.4641-4652. (10.1039/c4ce00070f)
- Thangavelu, S. G. et al., 2013. Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers. Inorganic Chemistry 52 (4), pp.2060-2069. (10.1021/ic3024698)
- Thangavelu, S. G. , Pope, S. J. A. and Cahill, C. L. 2015. Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands. Crystengcomm 17 (32), pp.6236-6247. (10.1039/C5CE00984G)
- Thorp-Greenwood, F. L. et al. 2009. Syntheses, structural studies and spectroscopic characterisation of pyridyl-phthalimide complexes of fac-(CO)(3)Re-I-diimines. Journal of Organometallic Chemistry 694 (9-10), pp.1400-1406. (10.1016/j.jorganchem.2008.12.048)
- Titos-Padilla, S. et al., 2013. Photophysical properties of [Ir(tpy)2]3+-doped silica nanoparticles and synthesis of a colour-tunable material based on an Ir(core)–Eu(shell) derivative. Journal of Materials Chemistry C 1 (24), pp.3808-3815. (10.1039/c3tc30466c)
- Yeo, B. R. et al. 2010. The Re(I) coordination chemistry of a series of pyrido[2,3-b]pyrazine-derived ligands: Syntheses, characterisation and crystal structures. Polyhedron 29 (3), pp.1088-1094. (10.1016/j.poly.2009.11.013)
- Young, T. B. et al. 2023. Chemically recyclable fluorescent polyesters via the ring-opening copolymerization of epoxides and anhydrides. Polymer Chemistry (10.1039/D3PY00209H)
Book sections
- Amoroso, A. J. and Pope, S. J. 2024. Lanthanides for luminescent and magnetic resonance imaging. In: Feng, L. and James, T. D. eds. Imaging Tools for Chemical Biology. Chemical Biology Royal Society of Chemistry. , pp.48-70. (10.1039/9781837673117-00048)
- Coogan, M. P. and Pope, S. J. A. 2015. Application of d- and f-block fluorescent cell imaging agents. In: Long, N. and Wong, W. eds. The Chemistry of Molecular Imaging. USA: Wiley-Blackwell. , pp.275-298. (10.1002/9781118854754.ch12)
- Gunnlaugsson, T. and Pope, S. J. 2014. Chapter 6: lanthanide ion complexes as chemosensors. In: Bettencourt-Dias, A. ed. Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials. Wiley-Blackwell. , pp.231. (10.1002/9781118682760.ch06)
- Lloyd, D. , Coogan, M. P. and Pope, S. J. 2012. Novel metal-based luminophores for biological imaging. In: Geddes, C. D. ed. Reviews in Fluorescence 2010. Reviews in Fluorescence Vol. 7.New York: Springer. , pp.15-44. (10.1007/978-1-4419-9828-6_2)
Research
- luminescent complexes for targeted biological imaging
- photoactive materials for lighting harvesting and energy applications
- earth abundant metal complexes for sustainable energy applications
- development of carbon nanomaterials
All of the work undertaken in our group involves a wide variety of organic and inorganic synthetic chemistry with a strong emphasis on spectroscopic characterisation. Our recent work has investigated new ligand frameworks for luminescent chromium(III), rhenium(I), iridium(III), platinum(II) and gold(I) complexes, as well as lanthanide based systems. We have developed metal complexes that have useful applications in bioimaging and are interested in the targeted behaviour and design of such systems, including the use of signal peptides.
We also develop metal complexes for high efficiency energy upconversion performance, which has broad application to photocatalysis and solar cell technologies. We are also actively pursuing the development of doped and surface functionalised nanoparticles for a range of materials applications. Recent work has described the surface chemistry of nanodiamonds to produce luminescent hybrid materials.
See 'Publications' tab for a full list of our recent research activity and outputs.
We collaborate widely and are always looking to develop new partnerships with academics and industry.
For more information on specific projects available with Professor Simon Pope please review the Molecular synthesis section of our research project themes.
Teaching
CH5208 Applications of Molecular Spectroscopy (Module Leader)
CH5202 Structure, Bonding and Reactivity in Compounds of the p- and d-block Elements
CH3307 Advanced Spectroscopy and Diffraction
CH3403/CHT237 Bioimaging Applications of Coordination Compounds (Module Leader)
Biography
BSc and PhD University of Southampton (2000, supervisor Prof Gillian Reid).
Postdoctoral Research Associate, University of Bristol (2000-2, Prof Michael D. Ward).
Postdoctoral Research Associate, University of Manchester (2002-6, supervisor Prof Stephen Faulkner).
Appointed as Lecturer, Cardiff, in 2006; promoted to Personal Chair in 2017.
Supervisions
- design, synthesis and characterisation of luminescent molecules
- photoactive materials for energy applications (photoredox, light harvesting, energy upconversion)
- development of molecular probes for biosensors and bioimaging
- functionalised carbon nanomaterials (carbon dots, nanodiamonds)
I welcome applications from self-funded postgraduate students. Please contact me to discuss potential PhD project ideas that are of interest to you and your funders..
Current supervision
Deemah Alenazy
Emily Judd-Cooper
Ibrahim Saleh Alkhaibari Alkhaibari
Allie Ibbott
Ben Christie
Basheer Alrashidi
Past projects
Examples of previous PhD thesis titles from the group:
- "Design and synthesis of luminescent probes aimed at biologically important targets"
- "Tuning the photophysics of Ir(III) and Pt(II) complexes by synthetic modification of quinoxaline ligands"
- "Developoment of new DNA-binding Sensitisers for biosensors"
- "A spectroscopic investigation of Cr(III) complexes"
- "Fluorescent nanodiamond: bioengineered functional materials"
- "Red emitting iridium(III) and rhenium(I) complexes developed for photonic applications"
- "Luminescent and electrochemical probes based on Au(I), Ir(III) and Fe(II) coordination complexes for bioimaging, diagnostics and therapeutics"
- "Element specific smart media for fast, low cost, radionuclide analysis"
- "Amphiphilic ligand architectures for s-, d- and f-block metallosurfactants towards micellar systems and microemulsions"
- "Development of luminescent iridium(III) and rhenium(I) complexes for optoelectronic applications"
Contact Details
Research themes
Specialisms
- Inorganic chemistry